PFAS-Free Coating Additives
Evaluate surface-control alternatives against substrate wetting, leveling, cratering and downstream adhesion requirements, with an explicit PFAS declaration scope.
General technical information published by PAXOMER Inc. to support preliminary material evaluation. It is compiled from the sources cited on this page and has not been independently reviewed or certified by a professional engineer, laboratory or certification body. Values marked typical, illustrative or requiring confirmation are not specifications. Confirm properties, standard editions, regulatory status and suitability for your specific application with the manufacturer and, where the use is regulated or safety-related, with a qualified professional or the relevant authority.
1. Quick answer
PFAS replacement is a function-by-function formulation task. A coating may need wetting, slip, leveling or foam control; a single replacement is not assumed to reproduce every function of the incumbent. Silicone-containing and silicone-free options must be screened separately where recoatability or contamination sensitivity matters.
2. What is the product, and what function does it perform?
PFAS replacement is a function-by-function formulation task. A coating may need wetting, slip, leveling or foam control; a single replacement is not assumed to reproduce every function of the incumbent. Silicone-containing and silicone-free options must be screened separately where recoatability or contamination sensitivity matters.
Educational qualification guidance. No manufacturer agreement, stocked grade, certification, sample availability or equivalence is established. All numerical limits must come from a verified grade and an agreed test method.
3. Which technical differences distinguish the candidates?
| Candidate class | Purpose to evaluate | Qualification boundary |
|---|---|---|
| Silicone-containing surface control | Wetting, slip and surface-tension adjustment | Check intercoat adhesion, foam and surface migration |
| Silicone-free leveling additive | Flow and leveling evaluation | Verify wetting on the actual low-energy substrate |
| Nonfluorinated wetting candidate | Substrate coverage screening | Confirm dynamic application behavior and compatibility |
4. How should buyers select a candidate for the application?
| Application | Buyer information | Acceptance trial |
|---|---|---|
| Waterborne coating | Binder, cosolvent, surfactant package and drying profile | Drawdown and application trial on production substrate |
| UV-curable ink or varnish | Cure system, film weight and substrate treatment | Wetting, cure, blocking and adhesion after aging |
| Solvent-borne industrial coating | Solvent balance, bake and recoat window | Appearance and multilayer adhesion |
5. What information should a structured specification request contain?
| Specification field | Information to request | Evidence and interpretation |
|---|---|---|
| PFAS declaration | Definition, intentionally added substances, scope and revision date | Supplier declaration plus buyer-agreed analytical scope if required |
| Carrier and active content | Carrier identity; active fraction with method | Compare active material, not only as-supplied dosage |
| Surface and appearance | Dynamic/static method, gloss and defect criteria | Agree substrate preparation and coating thickness |
6. How should an application trial establish acceptance?
Start with the control formulation and identify which incumbent functions are essential. Screen candidate and control at documented active-content bases, keeping substrate preparation, application speed and film thickness fixed. Record foam, craters, gloss and recoat adhesion both initially and after storage.
- Obtain exact-grade TDS and SDS before handling; follow supplier guidance for addition order, storage and equipment.
- Agree acceptance limits, sample identifiers and measurement conditions before the first comparison.
- Retain formulation, batch and process records; repeat promising conditions to check reproducibility before scale-up.
7. What limitations and tradeoffs affect selection?
A smoother film can still fail a later printing or recoating operation. If wetting improves while adhesion falls, investigate migration, contamination and cure before increasing addition. A fluorine-related analytical result does not by itself establish every possible PFAS claim.
8. What should a technical enquiry include?
Send the following requirements so an inquiry can be assessed against an actual application: Binder; aqueous/solvent/UV system; substrate and pretreatment; incumbent function; silicone tolerance; coating method; recoat/print requirements; required PFAS definition.
State trial quantity, recurring demand, destination, timing, required origin and document needs. Commercial capability, export suitability and terms require separate confirmation. No purchasing commitment is created by this page.
9. What evidence is required before approval?
Require grade identity, revision-controlled TDS/SDS, declaration scope, representative trial results and agreed lot acceptance. Ask how changes in composition or production are communicated. Record unresolved questions instead of inferring a specification from a family name.
10. Which sources support the guidance, and what are their limits?
BYK: PFAS-free surface additives (opens in a new tab)
Public manufacturer sources establish family/function context only. They do not establish PAXOMER authorization, an offer or applicability of a named grade. Trial plans and buyer-request fields on this page are planning aids that need qualified technical review before use. No full product dossier or restricted-substance declaration was obtained.
11. How should an application trial establish acceptance?
Replace the required function, not merely a chemical label. Identify whether the incumbent contributes foam control, wetting, slip or another measured effect. Keep a reference coating and define acceptance for each affected function before choosing a candidate described as PFAS-free.
12. Which checks distinguish compatibility problems from process problems?
Agree a written material-declaration scope for the exact grade and its supplied carrier. Qualify incorporation, coating appearance, storage and downstream operations independently of that declaration. A candidate can meet an agreed composition criterion and still fail the coating performance requirement.
13. Which technical differences distinguish the candidates?
| Question | Evidence to record | Interpretation limit |
|---|---|---|
| Composition objective | Grade-specific declaration with a defined scope | Does not prove coating performance |
| Functional objective | Compare the function supplied by the incumbent | An equal addition rate is not assumed |
| Compatibility | Inspect surface defects and formulation stability | Test the complete binder/pigment system |
| Downstream operation | Recoating, printing or bonding where required | Do not stop after a visually acceptable first coat |
14. Which manufacturer documents support the purchasing decision?
Ask manufacturers to identify candidate functions and provide current technical and safety documents plus an appropriately scoped declaration. Record formulation version, incorporation and test conditions. BYK presents PFAS-free additive solutions, including defoamer examples; the label does not establish blanket compliance or direct interchangeability across product families.
15. Which sources support the guidance, and what are their limits?
BYK: PFAS-free additive solutions (opens in a new tab)
16. Separate fluorine-related claims from coating-surface performance
A change away from a fluorinated additive may require a different balance of wetting, slip, levelling and foam control. Begin with the role of the incumbent, the coating binder and the application method. Avoid assuming that one replacement ingredient reproduces every function of a previous package.
Define the PFAS declaration scope separately from the functional trial. Ask what the supplier’s statement covers and how it aligns with the buyer’s requirement. A chemical-family substitution can change surface enrichment, recoating and stain or cleaning response. Test the actual multilayer construction and intended exposure rather than a single fresh drawdown.
Use clear acceptance photographs, controlled panels and relevant measurements for appearance, adhesion and subsequent processing. Keep dosage basis, mixing sequence, cure and film thickness consistent. Do not describe a candidate as universally compliant, non-toxic or environmentally superior merely because a selected substance family is excluded.
17. How should production problems be investigated?
Use the observations below to structure an investigation. They identify possible mechanisms, not a diagnosis from appearance alone. Compare candidate and control under the same defined conditions.
| Observed issue or decision | What to check | Qualification implication |
|---|---|---|
| Acceptable wetting but excess slip | Changed surface function and end-use friction requirement | Set distinct wetting and handling criteria |
| First coat passes; recoat fails | Surface migration, cure and next-layer compatibility | Approve the whole coating sequence |
| Ambiguous PFAS-free wording | Definition, scope and responsible-party evidence | Clarify the claim before public commercial copy |
18. Which sources support the guidance, and what are their limits?
These references support the named material or test scope. They do not establish supplier representation, a complete claim audit or a PAXOMER product approval.
https://local.byk.com/products/additives-for-the-coatings-industry (opens in a new tab)
19. How should a non-fluorinated surface-additive substitution be validated?
Define the claimed chemical scope separately from performance. Obtain a supplier statement for the exact grade and ask what the statement covers. Run wetting, appearance, foam and downstream adhesion checks in the complete formulation. A replacement that improves spreading may change slip or recoat behaviour. Do not infer a complete formulation's fluorine status from one additive's marketing label.
20. What should a PFAS-related declaration say before a coating additive is shortlisted?
Ask the supplier to identify the exact product, production scope, declaration date and definition being used. A statement about intentionally added ingredients, a targeted analytical result and a complete composition declaration answer different questions. Preserve the original wording; do not shorten a qualified statement into an absolute absence claim. Definitions and applicable obligations require destination-specific review.
Hypothetical reporting example: a laboratory result of “less than 10 mg/kg” under a named method means below that reported threshold for the stated analyte and sample. It does not mean zero, and it does not establish the absence of every substance in a broad chemical class. The invented threshold is not a legal limit, a recommended detection limit or an actual product result.
21. How should a PFAS-related additive substitution trial be evaluated?
Agree the control and decision criteria before the trial.
| Record | What to define | Comparison boundary |
|---|---|---|
| Declaration | Definition, product identity, scope and revision | Keep supplier statement and analytical evidence distinct. |
| Function | Wetting, slip, levelling, defoaming or another required effect | Define the function before choosing a replacement direction. |
| Application | Substrate, coating system and processing route | Use the intended finished coating. |
| Decision | Functional results, adverse effects and declaration review | Avoid approving from a label alone. |
22. Which observations can change the substitution decision?
If the candidate passes a declaration check but changes coating defects, evaluate function and compatibility under a controlled trial. Record which surface-control role the original additive provided. A composition statement cannot demonstrate that a substitute will produce the same appearance, application window or downstream adhesion.
23. Frequently asked questions
Does PFAS-free mean silicone-free?
No. These describe different chemistry constraints; require separate declarations.
Is there one drop-in fluorosurfactant replacement?
No universal replacement is established. Compare the needed functions in the full formulation.
Can a declaration replace an application trial?
No. Composition evidence and coating performance answer different questions.
What numerical dosage or limits apply?
No universal dosage or numerical specification is supplied. Use exact-grade documentation and a controlled formulation trial.
What is needed before procurement approval?
Confirm grade identity, documents, buyer acceptance trials and commercial capability separately.
Is this page a confirmed PAXOMER offer?
No. It is general educational information to support qualification planning.
Is a PFAS-free additive automatically a drop-in replacement?
No. The replacement may have a different functional balance and needs complete-formulation trials.
Does removing one additive establish environmental superiority?
No. Environmental comparisons require defined scope and appropriate evidence.
Why check recoating after a surface-additive change?
The changed surface may interact differently with a later coating or adhesive.
Does replacing one fluorinated additive prove the whole coating is PFAS-free?
No. Review every relevant input and the claim definition; analytical and supplier evidence must match the intended statement.
Does “not detected” mean a substance is absent?
No. Interpret the stated analyte, method, sample and reporting threshold. An analytical result has a defined scope.
Does a supplier declaration prove equivalent coating performance?
No. Review the declaration and the functional coating trial as separate parts of qualification.
Is the example threshold a legal limit?
No. It is invented solely to explain reporting language; applicable obligations require current destination-specific review.
24. References
Links inside sections are supplier or standards-body context for the statements they accompany.
Last revised 2026-10-27.
Related guides
- Silicone Wetting & Surface-Control Additives
- Specialty Coating Additives: Dispersion, Flow & Application
Explore further
Product and material pages
- Silicone Surface-Control Additives
- Industrial Coating Additives
- PFAS-Free Additives for Coatings & Inks
Material card: PFAS-Free Coating Additives (listed in Products & Solutions).
Glossary terms
Drop-in replacement · Functional equivalence